I think this community is more for questions with factual answers that have simply eluded you, not questions where the answers are opinions.
That said…
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Ryoji Kaji from Neon Genesis Evangelion
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Mamoru Chiba (AKA Tuxedo Mask) from Sailor Moon - my favorite look of his is when he’s in his brainwashed Prince Endymion form
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Spike Spiegel from Cowboy Bebop
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Hei from Darker Than Black
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Howl from Howl’s Moving Castle
Just rewatched Into Darkness. It still holds up, if the whitewashing doesn’t bother you.