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Just in case you are still curious, and I don’t see any actual answers here. The download provided is all the code for the game engine and everything else that would be going on in the background of the game. Anything that could be copyrighted by Nintendo (things like character and object models, textures, music, and environments) need to come from a totally legit dump from an official Nintendo cartridge and definitely not any ol’ .rom file you can download online
Spiderman 64 starts off exactly how you describe the game you remember. There is a tutorial, you stop a bank robbery, and then you have to save J Jonah Jameson by fighting Scorpion. Looked up some videos of the Scorpion fight, but it doesn’t look like he has a grab attack.
It was released on the Nintendo 64 in 2000. Not sure how different the ports are, but the game was ported to the PC in 2001, and to Mac in 2002.